5. LeBron James – 2006
The third and final LeBron segment on this list, this was one of his most impressive All-Star performances because he was so young. In fact, he broke the record for the youngest player in history to win the All-Star Game MVP award. He was just 21 at the time. That’s a sensational achievement.
James scored 29 points and grabbed six rebounds on the night in Houston, Texas. The East was trailing by 21 points when James turned up the heat and went on a scoring bonanza. In the end, they ran out winners by 122-120. LeBron had arrived and the world knew it.