36. Duke vs. Tennessee (1999)
The women’s tournament doesn’t receive the same attention as the men’s. Nonetheless, it’s still exciting and produces some shocking moments. This was one of the most dramatic because Tennessee was a basketball powerhouse. They won three consecutive titles before they ran into the Blue Devils.
By all rights, Tennessee should have won this game. However, Duke didn’t read the script. The number three seed shut down Chamique Holdsclaw and won the game, 69-63. Then they progressed to the Final Four. It was a massive shock (via New York Times).